有機(jī)合成現(xiàn)代方法

前言

This book is addressed principally to advanced undergraduates and to graduates at the beginning of their research careers, and aims to bring to their notice some of the reactions used in modern organic syntheses. Clearly, the whole field of synthesis could not be covered in a book of this size, even in a cursory manner, and a selection has had to be made. This has been governed largely by consideration of the usefulness of the reactions, their versatility and, in some cases, their selectivity.

內(nèi)容概要

The fourth edition of this well-known textbook discusses the key methods used inorganic synthesis, showing the value and scope of these methods and how they areused in the synthesis of complex molecules. All the text from the third edition hasbeen revised, to produce a modem account of traditional methods and an up-to-datedescription of recent advancements in synthetic chemistry. The textbook maintainsa traditional and logical approach in detailing carbon--carbon bond formations,followed by a new chapter on the functionalization of alkenes and concluding withoxidation and reduction reactions. Reference style has been improved to includefootnotes, allowing easy and rapid access to the primary literature. In addition, aselection of problems has been added at the end of each chapter, with answersat the end of the book. The book will be of significant interest to chemistry andbiochemistry students at advanced undergraduate and graduate level, as well asto researchers in academia and industry who wish to familiarize themselves withmodem synthetic methods.

作者簡(jiǎn)介

作者：(英國(guó))卡如薩 (Carruthers.W.)

書籍目錄

Preface to the first editionPreface to the fourth edition1 Formation of carbon-carbon single bonds  1.1   Main-group chemistry    1.1.1  Alkylation of enolates and enamines    1.1.2 Conjugate addition reactions of enolates and enamines    1.1.3  The aldol reaction    1.1.4  Asymmetric methodology with enolates and enamines    1.1.5 Organolithium reagents    1.1.6 Organomagnesium reagents    1.1.7  Organozinc reagents    1.1.8  Allylic organometallics of boron, silicon and tin  1.2  Transition-metal chemistry    Problems    1.2.1  Organocopper reagents    1.2.2  Organochromium chemistry    1.2.3  Organocobalt chemistry    1.2.4 Organopalladium chemistry2 Formation of carbon-carbon double bonds  2.1   B-Elimination reactions  2.2   Pyrolytic syn eliminations  2.3   Fragmentation reactions  2.4   Alkenes from hydrazones  2.5   Alkenes from 1,2-diols  2.6   Alkenes from alkynes  2.7   The Wittig and related reactions  2.8   Alkenes from sulfones  2.9   Alkenes using titanium or chromium reagents  2.10  Alkene metathesis reactions  Problems3 Pericyclic reactions   3.1   The Diels-Alder cycloaddition reaction       3.1.1  The dienophile       3.1.2 The diene       3.1.3  Regiochemistry of the Diels-Alder reaction       3.1.4 Stereochemistry of the Diels-Alder reaction       3.1.5 Intramolecular Diels-Alder reactions       3.1.6 The retro Diels-Alder reaction       3.1.7  Asymmetric Diels-Alder reactions   3.2   [2+2] Cycloaddition reactions   3.3   Cycloaddition reactions with allyl cations and allyl anions   3.4   1,3-Dipolar cycloaddition reactions   3.5   The ene reaction   3.6   [3,3]-Sigmatropic rearrangements       3.6.1  The Cope rearrangement       3.6.2 The Claisen rearrangement   3.7   [2,3]-Sigmatropic rearrangements   3.8   Electrocyclic reactions       Problems4 Radical and carbene chemistry   4.1  Radicals      4.1.1  Radical abstraction reactions      4.1.2 Radical addition reactions   4.2 Carbenes   Problems5 Functionalization of alkenes    5.1  Hydroboration       5.1.1  Reactions of organoboranes    5.2 Epoxidation and aziridination       5.2.1  Epoxidation       5.2.2 Asymmetric epoxidation       5.2.3  Aziridination……6 Oxidation7 ReductionAnswers to problemsIndex

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《有機(jī)合成現(xiàn)代方法(第4版)》為經(jīng)典英文化學(xué)教材系列之一，由世界圖書出版公司出版。

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