物理化學(xué)簡(jiǎn)明雙語(yǔ)教程

前言

隨著中國(guó)與世界的接軌和世界經(jīng)濟(jì)一體化的進(jìn)程，迫切需要大量精通英語(yǔ)的人才。作為一種培養(yǎng)國(guó)際化人才的有效手段，雙語(yǔ)教學(xué)勢(shì)在必行。國(guó)家教育部也在2002年提出加強(qiáng)大學(xué)本科教學(xué)的12項(xiàng)措施中，要求各高校在三年內(nèi)開(kāi)設(shè)5%-10%的雙語(yǔ)課，并引進(jìn)原版教材和編寫(xiě)雙語(yǔ)教材。開(kāi)設(shè)物理化學(xué)雙語(yǔ)課，可以幫助學(xué)生擴(kuò)大專(zhuān)業(yè)和非專(zhuān)業(yè)英語(yǔ)詞匯量，提高學(xué)生的英語(yǔ)水平，開(kāi)闊視野。原版物理化學(xué)教材一方面價(jià)格很昂貴，另一方面也不完全適合國(guó)內(nèi)大學(xué)本科學(xué)生的學(xué)習(xí)。編寫(xiě)一套在效度、信度、難度各方面都符合教學(xué)要求的雙語(yǔ)教材，不僅可以減少教師的備課難度和工作量，而且對(duì)激發(fā)學(xué)生專(zhuān)業(yè)學(xué)習(xí)的興趣也大有幫助。這本《物理化學(xué)簡(jiǎn)明雙語(yǔ)教程》對(duì)教學(xué)基本要求所規(guī)定的內(nèi)容采用漢語(yǔ)和英語(yǔ)兩種語(yǔ)言形式編寫(xiě)，便于教師和學(xué)生理解與學(xué)習(xí)。本教材各章內(nèi)容結(jié)構(gòu)如下：第一章氣體的pVT性質(zhì)；第二章熱力學(xué)第一定律；第三章熱力學(xué)第二定律；第四章多組分系統(tǒng)熱力學(xué)；第五章化學(xué)平衡；第六章相平衡；第七章電解質(zhì)溶液；第八章電化學(xué)系統(tǒng)；第九章界面現(xiàn)象；第十章化學(xué)動(dòng)力學(xué)。其中，第一至第六章主要由何美編寫(xiě)，第七至第十章主要由周華鋒編寫(xiě)。此外，參與本書(shū)編寫(xiě)的還有侯純明、張麗清、王雅靜、李云等老師。另外，為了與《物理化學(xué)簡(jiǎn)明雙語(yǔ)教程》這一教材配套，我們還編寫(xiě)了物理化學(xué)雙語(yǔ)解題指導(dǎo)：《物理化學(xué)雙語(yǔ)基礎(chǔ)》，以方便學(xué)生學(xué)習(xí)使用本教材。該解題指導(dǎo)已經(jīng)由中國(guó)石化出版社出版發(fā)行。由于編者水平有限，書(shū)中錯(cuò)誤和不當(dāng)之處在所難免，歡迎讀者批評(píng)指正。

內(nèi)容概要

　　《高等院校“十一五”規(guī)劃教材：物理化學(xué)簡(jiǎn)明雙語(yǔ)教程》編寫(xiě)是為了適應(yīng)物理化學(xué)雙語(yǔ)教學(xué)這一全新的教學(xué)模式，解決物理化學(xué)雙語(yǔ)教材短缺的問(wèn)題。在編寫(xiě)的過(guò)程中盡量做到內(nèi)容精練、簡(jiǎn)明易懂，并對(duì)每一部分重點(diǎn)內(nèi)容均采用英、漢雙語(yǔ)進(jìn)行編寫(xiě)。《高等院?！笆晃濉币?guī)劃教材：物理化學(xué)簡(jiǎn)明雙語(yǔ)教程》共分十章，內(nèi)容包括：氣體的pVT性質(zhì)；熱力學(xué)第一定律；熱力學(xué)第二定律；多組分系統(tǒng)熱力學(xué)；化學(xué)平衡；相平衡；電解質(zhì)溶液；電化學(xué)；界面現(xiàn)象；化學(xué)動(dòng)力學(xué)。

書(shū)籍目錄

Introduction0.1 Physical chemistry0.1.1 Contents of physical chemistry0.1.2 Issues to be solved by physical chemistry0.1.3 Advice for studying physical chemistry0.2 Indication and operation of physical quantity0.2.1 Indication of physical quantity0.2.2 Operation of physical quantityChapter 1 The pVT properties of gases1.1 State equation of the perfect gas1.1.1 Empirical law of gas1.1.2 State equation of the perfect gas1.1.3 Model of the perfect gas1.2 Mixture of the perfect gas1.2.1 Composition of perfect gas mixture1.2.2 Dalton’S law of partial pressures1.2.3 Amagat’S law of partial volumes1.2.4 Mean molar mass of mixed gas1.3 Liquefaction of real gas and critical properties1.3.1 Saturated vapor pressure of liquid1.3.2 Liquefaction of real gas and critical properties1.4 State equations of real gas1.4.1 The van der Waals equation1.4.2 The virial equation of state1.5 The law of corresponding states1.5.1 Compression factors1.5.2 The law of corresponding states。EXERCISESChapter 2 The first law of thermodynamics2.1 The basic concept of thermodynamics2.1.1 System and surroundings2.1.2 Extensive property and intensive property of system2.1.3 State and state function of system2.1.4 Equilibrium state of thermodynamics2.1.5 Process and path2.2 The first law of thermodynamics2.2.1 Heat2.2.2 Work2.2.3 Calculation of volume work2.2.4 Thermodynamic energy2.2.5 The first law of thermodynamics.2.3 The heat at constant volume.the heat at constant pressure and enthalpy2.3.1 The heat at constant volume2.3.2 The heat at constant pressure2.3.3 Enthalpy.2.3.4 Hess’s Law2.4 Heat capacity2.4.1 Heat capacity2.4.2 Relation between Cp,mand P2.4.3 Empirical formula between Cp,m and T2.4.4 Relation between Cp,m and Cv,m2.4.5 Joule experiment2.5 Reversible process and equation of adiabatic reversible process of the perfect gas2.5.1 Reversible process2.5.2 Isothermal reversible process of the perfect gas.2.5.3 Adiabatic reversible process of the perfect gas2.6 Phase transformation process.2.6.1 Phase and enthalpy of phase transition.2.6.2 Calculation of AH of phase transformation process2.7 Standard molar enthalpy of reaction2.7.1 Chemical stoichiometric number2.7.2 Extent of a reaction2.7.3 Molar enthalpy of reaction2.7.4 Standard molar enthalpy of reaction2.8 Standard molar enthalpy of formation and standard molar enthalpy of combustion2.8.1 Standard molar enthalpy of formation2.8.2 Standard molar enthalpy of combustion2.8.3 The temperature—dependence of A，n(T)一Kirchhoff’S formula.2.8.4 The relation between Qp and Qv.2.8.5 Maximum temperature of explosion and flame reaction2.9 Throttling process and Joule—Thomson effect2.9.1 Joule—Thomson experiment2.9.2 Experiment result2.9.3 Result analysis2.9.4 Characteristice of throttling process2.9.5 Joule-Thomson coefficientEXERCISESChapter3 The Second Law of thermodynamicsChapter4 The thermodynamics of multi-component systemsChapter5 Chemical equilibriumChapter6 Phase equilibriumChapter7 Electrolyte solutionChatper8 Electrochemical systemChapter9 Interface phenomenaChapter10 Chemical KineticsREFERENCE BOOKS

章節(jié)摘錄

Introduction（緒論）0.1 Physical chemistry（物理化學(xué)）Physical chemistry studies the underlying physical principles that govern the Properties and behavior of chemical systems. It is the subject which start with the connection of physical phenomenon and chemical phenomenon, then utilize physical theories and experimental methods to look forThe rules of chemical change.A chemical system can be studies from either a microscopic or a macroscopic viewpoint. The microscopic viewpoint makes explicit use of the concept of molecules. The macroscopic viewpoint studies large-scale properties of matter without explicit use of the molecule concept.0.1.1 Contents of physical chemistry（物理化學(xué)的研究?jī)?nèi)容）We can divide physical chemistry into four main areas: thermodynamics, quantum chemistry, statistical mechanics, and kinetics.Thermodynamics（熱力學(xué)）is a macroscopic science that studies the interrelation-ships among the various equilibrium properties of a system.Molecules and the electrons and nuclei that compose them do not obey classical(Newtonian) mechanics; instead their motions are governed by the laws of quantum mechanics. Application of quantum mechanics to atomic structure, molecular bonding, and spectroscopy gives us quantum chemistry（量子化學(xué)）.

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《物理化學(xué)簡(jiǎn)明雙語(yǔ)教程》既可作為高等院校雙語(yǔ)物理化學(xué)教學(xué)的教材使用，也可以作為非雙語(yǔ)物理化學(xué)教學(xué)的參考教材。

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