出版時間:2008-8 出版社:哈爾濱工業(yè)大學出版社 作者:鄭衛(wèi) 主編 頁數(shù):326 字數(shù):292000
內容概要
本書介紹了電化學中常用的一些基本概念、基本原理及常用的研究地,如循環(huán)伏安法、交流阻抗法、極譜法和脈沖伏安法,并介紹了電化學在腐蝕防護和生物電化學中的應用?! ”緯勺鳛殡娀瘜W專業(yè)的本科生教材,也可供從事電化學科學研究的科研工作者和技術人員參考。
書籍目錄
1 Introduction 1.1 The Scope of Electrochemistry 1.2 The Nature ofElectrode Reactions 1.3 Thermodynamics and Kinetics 1.4 Methods for Studying Electrode Reactions 1.5 Applications of Eleetroeheraistry2 Introduction to the Fundamental Concepts of Electrochemistry 2.1 Introduction 2.2 Electrochemical Cells and Reactions 2.3 Electron Transfer 2.4 Mass Transport 2.5 The Interaction d Electron Transfer and Mass Transport 2.6 Coupled Chemical Reactions 2.7 Adsorption 2.8 Phase Formation3 Kinetics of Electrode Reactions 3.1 Intnxluefon 3.2 Essentials of Electrode Reactions 3.3 Bufle-Volmer Model of Electrode Kinetics 3.4 Implications of the Butler-Volmer Model for the One-step, One-electron Process 3.5 Multistep Mechanisms4 The Electrical Double Layer 4.1 Introduction 4.2 The Thermodynamics of Charged Interfaces 4.3 The Statute d the Electrical Double Layer 4.4 The Adsorption Isotherm 4.5 The Effect of Doubly Layer Structure on Electrode Kinetics 4.6 Experimental Methods5 Electrodamical Experiments 5.1 Introduction 5.2 Electro& Materials 5.3 The Working Electrode: Preparation and Cleaning 5.4 The CeU: Measurements at Equilibrium 5.5 The Cell: Measurements away from Equilihrium 5.6 Calibration of Electrodes and Cells 5.7 Insmanentation: General 5.8 Analgue Instrumentation6 Potential Sweep Techniques and Cyclic Voltammetry 6.1 Introduction 6.2 Reversible Reactions 6.3 Irreversible Systems 6.4 Coupled Homogeneous Reactions ……7 Polarography and Pulse Voltammetry8 Alternating Current Techniques9 Corrosion10 BioelectrochenistryReferences
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