物理化學(xué)導(dǎo)論

內(nèi)容概要

The third edition of this book has been completely revised. It is intended for first- and second-year undergraduates in chemistry, and for undergraduates in other science and engineering subjects which require an understanding of chemistry.    The author gives more attention to the solid and liquid states than is found in most other books on physical chemistry, and introduces topics such as computer simulation and quasicrystals, Each chapter concludes with a set of problems designed to lead the reader to familiarity with the subject and its application in new situations. Computer programs designed to assist the reader are downloadable from the Worldwide Web (www. cup. cam.ac.uk). Detailed solutions to the problems are available on the same internet, while brief answers are contained within the book itself. Stereoviews are presented for three-dimensional structures and instructions for viewing them are provided. The book assumes only pre-degree mathematics, and special mathematical and other topics are contained in appendices.    This modern text on physical chemistry will be of interest to undergraduate students in chemistry and also to students in other areas of science and engineering requiring a familiarity with the subject.

作者簡介

作者：（英國）Mark Ladd

書籍目錄

PrefacePhysical constants and other numerical data1 Structure， energy， mechanism  1.1 Introduction  1.2 Structure  1.3 Energy  1.4 Mechanism  Problems12 Atoms， molecules and their structures  2.1 Introduction  2.2 Classical mechanics  2.3 Conflict with experiment  2.4 Wave-particle duality  2.5 Quantum mechanics of particles  2.6 Vibrational and rotational motion  2.7 Structure of the hydrogen atom  2.8 Atoms with more than one electron  2.9 Aufbau principle  2.10 Ionization energy  2.11 Structures of molecules  2.12 Huckel molecular-orbital theory  2.13 Valence-shell electron-pair repulsion theory  2.14 Ligand-field theory  2.15 Apparently abnormal valence  Problems23 Determinatin of structure  3.1 Introduction  3.2 Symmetry concepts  3.3 Symmetry elements and symmetry operations  3.4 Group theory  ……4 Energy and energetics5 States of matter:gases and liquids6 States of matter:solids7 Phase rule and properties of solutions8 Chemical equilibrium9 Electrochemistray10 Chemical kinetics and mechanisms of chemical reactionsAppendix BibliographyAnswers to numerical problemsIndex

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