高分子物理

內(nèi)容概要

　　《高分子物理：“結(jié)構(gòu)與性能”背后的概念(英文版.原書第3版)》對高分子物理的多個領(lǐng)域作了生動而詳細的介紹，內(nèi)容涵蓋鏈構(gòu)象，高分子溶液，共混物和嵌段共聚物，半晶態(tài)聚合物，聚合物網(wǎng)絡(luò)，聚合物流體等多種體系。作者還使用了大量的數(shù)學處理與實驗結(jié)果，對提出的機理與數(shù)學模型進行示例與驗證，勾勒出一幅濃墨重彩的高分子物理畫卷。
　　《高分子物理：“結(jié)構(gòu)與性能”背后的概念(英文版.原書第3版)》可作為化學化工、材料科學和物理學等專業(yè)的本科生和研究生教材，也可供有關(guān)領(lǐng)域的專家、學者閱讀參考。

作者簡介

作者:(德)G.斯特羅伯

書籍目錄

出版說明
推薦序
preface（前言）
preface to the first edition/第1版前言
1constitution and architecture of chains/鏈的組成與構(gòu)造1
2single chain conformations /單鏈構(gòu)象15
2.1rotational isomeric states /旋轉(zhuǎn)異構(gòu)態(tài)15
2.2helices/螺旋19
2.3coils /線團22
2.3.1the ideal chain/理想鏈26
2.3.2the expanded chain/膨脹鏈45
2.4the persistent chain/持續(xù)鏈55
2.5the ising chain/ 伊辛鏈59
3polymer solutions /聚合物溶液69
3.1dilute and semidilute solutions/稀溶液與半稀溶液70
3.1.1osmotic pressure/滲透壓71
3.2screening of excluded volume forces/排除體積力的屏蔽82
3.3polyelectrolyte solutions/聚電解質(zhì)溶液89
3.3.1condensation and screening of charges /電荷的團聚與屏蔽89
3.3.2chain stretching, salt effects and interchain
ordering/鏈伸展、鹽效應(yīng)與鏈間序95
3.3.3osmotic pressure/滲透壓100
4polymer blends and block copolymers/共混物與嵌段共聚物105
4.1the flory?huggins treatment of polymer
mixtures/聚合物混合物的flory?huggins處理方法106
4.1.1phase diagrams: upper and lower miscibility
gap/相圖：上臨界與下臨界混溶間隙117
4.2phase separation mechanisms/相分離機理122
4.3critical fluctuations and spinodal
decomposition/臨界漲落與旋節(jié)線分解129
4.3.1critical scattering/臨界散射132
4.3.2decomposition kinetics/分解動力學143
4.4block copolymer phases/嵌段共聚物的相結(jié)構(gòu)151
4.4.1layered structures/層狀結(jié)構(gòu)155
4.4.2pretransitional phenomena/前轉(zhuǎn)變現(xiàn)象157
5the semicrystalline state/半結(jié)晶態(tài)165
5.1structure characteristics/結(jié)構(gòu)特征167
5.1.1morphological elements /基本形態(tài)167
5.1.2structure parameters/結(jié)構(gòu)參數(shù)173
5.2kinetics of crystallization and melting/結(jié)晶與熔融動力學181
5.3laws for the structure development/結(jié)構(gòu)變化規(guī)律190
5.3.1the multistage model/多階段模型199
5.4mechanisms of secondary crystallization/二級結(jié)晶機理205
5.4.1the insertion mode/插層模式208
5.4.2surface crystallization and melting/表面結(jié)晶與熔融212
5.5crystallization from oriented melts/取向熔體結(jié)晶216
6mechanical and dielectric response/力學與介電響應(yīng)223
6.1response functions/響應(yīng)函數(shù)224
6.1.1viscoelasticity/粘彈性224
6.1.2orientational polarization/取向極化228
6.1.3general relationships/通用公式229
contents6.2relaxatory modes/松弛模式236
6.2.1single?time relaxation process/單時間松弛過程237
6.2.2retardation and relaxation time spectra/推遲與松弛時間242
6.3specific relaxation processes and flow behavior/具體松弛過程與流動行為
245
6.3.1local processes/局部過程246
6.3.2glass?rubber transition and melt flow/玻璃?橡膠轉(zhuǎn)變與熔體流動250
6.3.3the glass transition temperature/玻璃化轉(zhuǎn)變溫度269
6.3.4relaxation in partially crystalline systems/半晶體系中的松弛277
7conjugated polymers/共軛聚合物287
7.1electrooptic activity/光電活性289
7.1.1excitons and free charges/激發(fā)與自由電荷289
7.1.2electroluminescence/電發(fā)光297
7.2effects of doping/摻雜效應(yīng)302
7.2.1electrical conductivity/電導率302
7.2.2magnetism and reflectivity/磁性與反射率306
8microscopic dynamics/微觀運動學313
8.1the fluctuation?dissipation theorem/漲落?耗散原理313
8.2the rouse model/rouse模型317
8.2.1stress relaxation/應(yīng)力松弛325
8.2.2the dielectric normal mode /介電基準模式330
8.3entanglement effects in polymer melts/聚合物熔體中的纏結(jié)效應(yīng)333
8.3.1the reptation model/爬行模型338
8.4solution viscosities/溶液粘度 343
8.4.1neutral polymers: hydrodynamic
interaction/中性聚合物：流體力學作用344
8.4.2polyelectrolytes: coulomb interaction/聚電解質(zhì)：靜電作用 352
9non?linear mechanics /非線性力學357
9.1rubber elasticity/橡膠彈性361
9.1.1the fixed junction model of ideal rubbers/理想橡膠的固定結(jié)點模型364
9.1.2the cauchy strain tensor/ cauchy應(yīng)變張量371
9.1.3finger?s constitutive equation/ finger本構(gòu)方程376
9.2swelling of neutral and electrolytic gels/中性與電解質(zhì)凝膠的溶脹384
9.3non?newtonian melt flow/非牛頓熔體的流動390
9.3.1rheological material functions /流變材料函數(shù)391
9.3.2the lodge liquid/ lodge液體398
9.3.3the stress?optical rule/應(yīng)力?光學規(guī)則404
10deformation, yielding and fracture/形變、屈服與斷裂415
10.1shear deformation in semicrystalline
polymers/半晶聚合物中的剪切形變418
10.1.1critical strains/臨界應(yīng)變418
10.1.2constituents of the drawing stress/拉伸應(yīng)力的成分426
10.1.3the mechanics of neck formation/細頸形成機理429
10.1.4fibrillar state of order/纖維化有序態(tài)435
10.2crazing/銀紋 444
10.3brittle fracture/脆性斷裂450
10.3.1linear fracture mechanics /線性斷裂力學453
10.3.2the slow mode of crack growth/裂縫生長的緩慢模式455
ascattering experiments/散射實驗463
a.1fundamentals/基本概念463
a.1.1basic equations/基本方程464
a.1.2time?resolved scattering experiments/時間分解的散射實驗468
a.2absolute intensities/絕對強度471
a.3low angle scattering properties/小角散射性質(zhì)474
a.3.1guinier?s law/ guinier公式474
a.3.2forward scattering/前散射476
a.4special polymer systems/特種聚合物體系477
a.4.1binary mixtures and block copolymers/二元混合物與嵌段共聚物477
a.4.2two?phase layer systems/兩相層狀體系484
bglossary of symbols/術(shù)語與符號493
cbibliography/參考書目501
references/參考文獻505
index/索引

章節(jié)摘錄

版權(quán)頁：   插圖：   Polymers，also known as macromolecules，are built up of a large number of molecular units that are linked together by covalent bonds．Usually they represent orgamc compoundg，containing carbon atoms together with hydrogen，oxygen，nitrogen，and halogens，etc．In this first chapter，we briefly survey the main characteristics of their chemical constitution and molecular architecture and introduce the notions employed for their description．using examples for the explanation． All these polymers are electrically neutral． If chains are built up of monomers that contain an ionizable group， i．e．， a group that can dissociate into a chain—fixed kation or anion and a mobile counter—ion bearing the opposite charge， a polyelectrolyte is obtained． Table 1．2 collects a few typical examples． The first three compounds are synthetic polymers， the other two samples are biopolymers； cellulose and starch in the form of derivatives which include ionizable substitutes．  Charges on a chain can also be created by doping processes． For conjugated polymers， i．e．， chains with conjugated C—C double bonds， this is particularly easy． Even more importantly， the produced charges are mobileand thus provide electrical conductivity． Table 1．3 compiles some of these special materials．

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