材料熱力學(xué)

內(nèi)容概要

　　《材料熱力學(xué)》將材料作為一個(gè)整體研究對(duì)象，內(nèi)容涵蓋金屬、合金、陶瓷、半導(dǎo)體和高分子等所有材料領(lǐng)域的宏觀、介觀和微觀熱力學(xué)，注重通過(guò)材料問(wèn)題實(shí)例來(lái)使讀者理解和掌握熱力學(xué)的基本規(guī)律。本書(shū)還以較大篇幅介紹了納米熱力學(xué)和界面熱力學(xué)的最新進(jìn)展，以及相關(guān)計(jì)算機(jī)模擬的最新貢獻(xiàn)?！恫牧蠠崃W(xué)》適用于所有材料相關(guān)領(lǐng)域的科研工作者、工程師和研究生。作者蔣青博士與文子博士為吉林大學(xué)教授。

書(shū)籍目錄

Chapter 1　Fundamentals of Thermodynamics　1.1　Thermodynamics of Materials Science, Scope and Special Features of the Book　1.2　Concepts of Thermodynamics　1.3　Temperature and Zeroth Law of Thermodynamics　1.4　First Law of Thermodynamics　1.5　Entropy and Second Law of Thermodynamics　1.6　General Thermodynamic Relationships　1.7　Third Law of Thermodynamics　ReferencesChapter 2　Statistical Thermodynamics　2.1　Basic Concepts　2.2　Classical Statistic Thermodynamics of Independent Particles　2.3　Energy Mode and Energy Levels　2.4　Bose-Einstein and Fermi-Dirac Statistics　2.5　Application of Quantum Statistics　　2.5.1　Spatial Configuration of Long Chain Polymers　　2.5.2　Statistical Thermodynamics of a Paramagnetic Crystal　　2.5.3　Negative Temperature　ReferencesChapter 3　Heat Capacity, Entropy, and Nanothermodynamics　3.1　Heat Capacity　　3.1.1　Relations of Principal Heat Capacities　　3.1.2　Magnetic Heat Capacity　　3.1.3　Heat Capacity of Lattice Vibration of Solids　　3.1.4　Electronic Heat Capacity of Metals　3.2　Entropy　　3.2.1　Positional Part of Melting Entropy and Its Evaluation　　3.2.2　Contribution of Vibrational Part of Melting Entropy of Semiconductors　　3.2.3　Electronic Component of Melting Entropy　3.3　Nanothermodynamics　3.4　Melting Thermodynamics　　3.4.1　A Melting Criterion　　3.4.2　Existing Models for Size-dependent Melting of Crystals　　3.4.3　Size-dependent Melting Thermodynamics of Crystals　3.5　Cohesive Energy　　3.5.1　Size-dependent Cohesive Energy of Crystals　　3.5.2　Vacancy Formation Energy and Cohesive Energy of Clusters　　3.6　Size Effect on Bandgap of II-VI Semiconductor Nanocrystals　ReferencesChapter 4　Phase Diagrams　4.1　Gibbs Phase Rule and Phase Diagram of Unary System　4.2　Clapeyron. Equation in Condensed State Equilibria　4.3　Solution, Partial Molar Properties and Chemical Potential　4.4　Graphical Representation, Ideal and Regular Solutions　4.5　Equilibrium Conditions of Phases and Phase Diagram of Binary Systems　　4.5.1　Complete Miscibility, Continuous Binary Solution Phase Diagram and Related Size Dependence　　4.5.2　Immiscibility-Two Mechanisms of Phase Transitions　4.6　On Approximation of Gibbs Free Energy Change of Crystallization　4.7　Bandgap Energy of Binary Nanosemiconductor Alloys　ReferencesChapter 5　Thermodynamics of Phase Transitions　5.1　Thermodynamic Classification of Phase Transitions　5.2　Landau and Ising Models for the Second-order Phase Transitions　　5.2.1　Landau Model　　5.2.2　Ising Model and its Applications　　5.2.3　Critical Exponent　5.3　Thermodynamics of Martensitic and Bainite Transitions　5.4　Glass Transition　　5.4.1　Freezing into Solid State: Glass Formation versus Crystallization　　5.4.2　Characteristic Properties of Glass Transition　　5.4.3　Size Effect on Glass Transition　5.5　Ferromagnetic and Antiferromagnetic Phase Transitions of Nanocrystals　　5.5.1　Size-dependent Ordering Temperatures of Ferromagnetic and Antiferromagnetic Nanocrystals　　　5.5.2　Thermal Stability in Exchange-biased FM/AFM Bilayers　　5.5.3　Ferroelectric Phase Transition of Nanocrystals　　5.5.4　Superconductive Phase Transition of Nanocrystals　ReferencesChapter 6　Thermodynamics of Interfaces　6.1　Point Defect Thermodynamics　6.2　Line Defects Thermodynamics　6.3　Thermodynamics of Interfaces　　6.3.1　Thermodynamic Description of Surface Free Energy of Liquids and Solids　　6.3.2　Thermodynamics of Surface Stress and Intrinsic Stress　　6.3.3　Real Surface: Reconstruction and Relaxation　　6.3.4　Equilibrium of Fluid Droplets and Solid Particles　　6.3.5　Wulff Construction and Adsorption on Solid Surfaces　6.4　Solid-liquid Interface Energy　　6.4.1　Bulk Solid-liquid Interface Energy and That at Melting Points　　6.4.2　Size Dependence of Solid-liquid Interface Energy　　6.4.3　Nucleus-liquid Interface Energy　6.5　Solid-solid Interface Energy　6.6　Solid-vapor Interface Energy or Surface Energy　　6.6.1　Bulk Surface Energy of Elementary Solids　　6.6.2　%v0 of Several Ceramics with NaC1 Structure　　6.6.3　Size-dependent Surface Energy of Solids　6.7　Liquid-vapor Interface Energy or Surface Tension　　6.7.1　Bulk Surface Tension and Its Temperature Coefficient　　6.7.2 Determination of Lv0（Tm） and /Lv0（Tm） Values and Lv0 （T） and /v0 （T） Functions　　6.7.3　Size Dependence of Liquid-vapor Interface Energy　 　6.8　Applications of Size-dependent Interface Energy　　6.8.1　Thermodynamic Phase Stability of Nanocarbons　　6.8.2　Static Hysteresis of Solid Transition of CdSe Nanocrystals　　6.8.3　Critical Layer Number and Critical Misfit of Epitaxia] Grown Metallic Thin Films　　6.8.4　Reconstruction Possibility of fcc Metallic Surfaces at Room Temperature　ReferencesIndex

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