出版時間:2007-4 出版社:科學(xué) 作者:貝希施泰特 頁數(shù):342
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內(nèi)容概要
本書以新穎的視角全面介紹了表面的幾何結(jié)構(gòu)和電子結(jié)構(gòu)。所涉及的表面包括共價鍵和離子健結(jié)合的固體表面以及金屬表面。本書重在基礎(chǔ)部分,比如表面結(jié)晶和熱力學(xué)原理,促使原子重新排列的力,成健與電子結(jié)構(gòu)之間的關(guān)系等。本書闡述了表面晶向、化學(xué)成分、熱力學(xué)條件以及由此產(chǎn)生的各種性質(zhì)之間的聯(lián)系,表面上的激發(fā)及其表述與測量。書中的討論和方法有助于讀者分析新型表面和新材料間的界面。本書是從事表面生長、表面分子相互作用、自組裝結(jié)構(gòu)、材料性能工程和新材料研究的科技工作者不可缺少的參考書。
書籍目錄
1.Symmetry1.1 Model Surfaces1.1.1 Surface Versus Bulk1.1.2 The Surface as a Physical Object1.2 Two-Dimensional Crystals1.2.1 Lattice Planes of Bulk Crystals1.2.2 Oriented Slabs1.2.3 Ideal Surfaces.Planar Point Groups1.2.4 Real Surfaces:Reconstruction and Relaxation1.2.5 Superlattices at Surfaces1.2.6 Wbod Notation1.2.7 Symmetry Classification1.3 Reciprocal Space1.3.1 Direct and Reciprocal Lattices1.3.2 Brillouin Zones1.3.3 Projection of 3D Onto 2D Brillouin Zones1.3.4 Symmetry of Points and Lines in Reciprocal Space2.Thermodynamics2.1 Kinetic Processes and Surfaces in Equilibrium2.2 Thermodynamic Relations for Surfaces2.2.1 Thermodynamic Potentials2.2.2 Surface Modification of Thermodynamic Potentials2.2.3 Surface Tension and Surface Stress2.3 Equilibrium Shape of Small Crystals2.3.1 Anisotropy of Surface Energy2.3.2 Absolute Values for Surfaee Energies2.3.3 Wulff Construction2.4 Surface Energy and Morphology2.4.1 Facetting and Roughening2.4.2 3D Vcrsus 2D Growth2.4.3 Formation of Quantum Dots2.5 Stoichiometry Dependence2.5.1 Thermodynamic Approach……3.Bonding and Energetics4.Reconstruction Elements5.Elementary Excitations Ⅰ:Single Electronic Quasiparticles6.Elementary Excitations Ⅱ:Pair and Collective Excitations7.DefectsReferencesIndex
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